Material Safety Data Sheet
FisherBrand General Purpose Cleaner
ACC# 88583
Section 1 - Chemical Product and Company Identification |
MSDS Name: FisherBrand General Purpose Cleaner
Catalog Numbers:
ACE414, 15-335-55OLD, 1533555, 1533555OLDON
Synonyms:
None.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7732-18-5 |
Water |
82 | 231-791-2 |
111-76-2 |
2-Butoxyethanol |
6 | 203-905-0 |
6834-92-0 |
Sodium metasilicate |
6 | 229-912-9 |
68439-57-6 |
Sodium C14-16-alkane hydroxy & alkene sufonates |
3 | 270-407-8 |
127087-87-0 |
4-Nonylphenol, branched, ethoxylated |
3 | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear red liquid.
Danger! Corrosive. Causes eye and skin burns. May
cause severe respiratory tract irritation with possible burns. May
cause severe digestive tract irritation with possible burns. May
cause central nervous system effects. May cause liver and kidney
damage.
Target Organs: Blood, kidneys, central nervous
system, liver, eyes, skin, mucous membranes.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Not available.
Prolonged skin contact may cause moderate irritation, defatting,
dermatitis. Overexposure may cause painful burns on exposed skin.
Ingestion:
Causes gastrointestinal tract burns. May cause central nervous
system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects. Central nervous
system effects, which appear to predominate in acute cases are
characterized by abnormal fatigue, memory difficulties and dizziness.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Effects may be delayed.
Hemolysis of red blood cells may lead to possible liver and kidney
Section 4 - First Aid Measures
|
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not get in eyes, on skin, or on clothing. Keep container tightly
closed. Discard contaminated shoes. Avoid breathing vapor or mist.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area. Keep away from acids.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Water
|
none listed
|
none listed
|
none listed
|
2-Butoxyethanol
|
20 ppm TWA
|
5 ppm TWA; 24 mg/m3 TWA 700 ppm IDLH
|
50 ppm TWA; 240 mg/m3 TWA
|
Sodium metasilicate
|
none listed
|
none listed
|
none listed
|
Sodium C14-16-alkane hydroxy & alkene sufonates
|
none listed
|
none listed
|
none listed
|
4-Nonylphenol, branched, ethoxylated
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
2-Butoxyethanol:
25 ppm TWA; 120 mg/m3 TWA
Sodium metasilicate:
No OSHA Vacated PELs are listed for this chemical.
Sodium C14-16-alkane hydroxy & alkene sufonates:
No OSHA Vacated PELs are listed for this chemical.
4-Nonylphenol, branched, ethoxylated:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear red
Odor: aromatic odor
pH: 12.3 @ use dilution
Vapor Pressure: Not available.
Vapor Density: >1.0
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: > 100 deg C
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:1.07
Molecular Formula:Not applicable.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Extreme temperatures.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 111-76-2:
KJ8575000
CAS# 6834-92-0:
VV9275000
CAS# 68439-57-6
unlisted.
CAS# 127087-87-0:
RB2451000; TR1581962
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 =
>90 mL/kg;
.
CAS# 111-76-2:
Dermal, guinea
pig: LD50 = 230 uL/kg;
Draize
test, rabbit, eye: 100 mg Severe;
Draize test, rabbit, eye: 100 mg/24H
Moderate;
Inhalation, mouse: LC50 =
700 ppm/7H;
Inhalation, mouse: LC50
= 3380 mg/m3/7H;
Inhalation, rat:
LC50 = 450 ppm/4H;
Inhalation, rat:
LC50 = 2900 mg/m3/7H;
Oral, mouse:
LD50 = 1230 mg/kg;
Oral, mouse:
LD50 = 1167 mg/kg;
Oral, rabbit:
LD50 = 300 mg/kg;
Oral, rabbit:
LD50 = 320 mg/kg;
Oral, rat: LD50 =
470 mg/kg;
Oral, rat: LD50 = 917
mg/kg;
Skin, rabbit: LD50 = 220
CAS# 6834-92-0:
Draize test,
rabbit, skin: 250 mg/24H Severe;
Oral, mouse: LD50 = 770 mg/kg;
Oral, rat: LD50 = 1153 mg/kg;
.
CAS# 68439-57-6:
.
CAS# 127087-87-0:
.
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 111-76-2:
- ACGIH:
A3 - Confirmed animal carcinogen with unknown relevance to humans
- California:
Not listed.
- NTP:
Not listed.
- IARC:
Not listed.
CAS# 6834-92-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 68439-57-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 127087-87-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
The high pH of this material makes it harmful to aquatic life.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. |
CORROSIVE LIQUID BASIC INORGANIC (CONTAINS SODIUM METASILICATE) |
Hazard Class: |
8 |
8 |
UN Number: |
UN3266 |
UN3266 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 111-76-2 is listed on the TSCA inventory.
CAS# 6834-92-0 is listed on the TSCA inventory.
CAS# 68439-57-6 is listed on the TSCA inventory.
CAS# 127087-87-0 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 111-76-2: Effective 4/13/89, Sunset 6/30/98
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 111-76-2: immediate, delayed, fire.
CAS # 6834-92-0: immediate.
Section 313
This material contains
2-Butoxyethanol (listed as Glycol ethers), 6%, (CAS# 111-76-2) which
is subject to the reporting requirements of Section 313 of SARA Title
III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 111-76-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 6834-92-0 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 68439-57-6 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 127087-87-0 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 111-76-2: 1
CAS# 6834-92-0: 1
CAS# 68439-57-6: No information available.
CAS# 127087-87-0: 2
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 111-76-2 is listed on Canada's DSL List.
CAS# 6834-92-0 is listed on Canada's DSL List.
CAS# 68439-57-6 is listed on Canada's DSL List.
CAS# 127087-87-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 111-76-2 is listed on the Canadian Ingredient Disclosure List.
CAS# 6834-92-0 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 12/01/1997
Revision #8 Date: 11/07/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.